If you're chemically sensitive, it's probably not a good idea to get it installed, but it's also not a good idea to breathe musty air from the crawl space either. In addition, your house and its contents are made of lots of materials that affect your indoor air quality. If you're really concerned about this, hire a company to test your air and tell you what you can do about it.
The local foam installer that I used here in Hilton Head told me he looked for some peeling back of the foam. This was ensuring that it was at the perfect temperature which helped them maximize their yield (profit). I have open cell foam and it pulled away a little, and did so immediately (within minutes). They went back after they were done to any spots that pulled away too much and filled them with the touch up kit; they were looking for the top edge to roll just a little bit. 
Spray foam insulation, when properly installed is both an air barrier and when closed cell foam is used at the proper depth a vapor barrier!  Before hiring any contractor you should establish the brand of foam being used and verify that with the named manufacture.  Please ask for ESR reports and MSDS sheets on any foam being installed in your home. A couple areas where you might consider spray foam insulation include:
One thing I wanted to mention was that I think your price point is a little high and that might deter people from considering spray foam. As a project manager for a spray foam company for years I can tell you that we offer 0.5 Lb. open-cell foam at around $.25/board foot. We even offer a 1.0 Lb. open-cell foam for less/the same cost as you quoted the 0.5 Lb. foam for above. The 1/0 Lb. open-cell foam has an R-value of almost 5.
One of the key differentiators between traditional insulation materials and spray foam insulation is the latter’s ability to insulate and air seal. Foam insulation provides an air barrier to wherever it is applied to help mitigate air leakage from the building. Air sealing the building envelope with sprayed-in foam insulation also helps address moisture ingress to reduce the risk of mold and mildew growth as well as the formation of ice dams in colder climate zones during the winter months.  When you compare foam insulation with traditional fiberglass insulation and cellulose insulation, sprayed insulation minimizes air infiltration, it assists in limiting moisture vapor from entering and escaping the home, which in turn reduces the load on heating and cooling systems. Below is a video that compares fiberglass, cellulose and open-cell spray foam in terms of insulating and air sealing value.

I don't even want to ask this question but... several years ago we hired a local contractor to spray high density foam on the roof deck and walls of our unfinished 2nd floor. We realized that the job was done poorly and cut an access into the attic space to assess things. We realize now that they spray foamed directly to the chimney (no flashing). The chimney is currently used for a woodstove and DHW venting. The DHW will go away but wood stove will remain. My question is, how bad (unsafe) is this? I have found information on foam exposure to fire but have not been able to find anything about temperature ratings in general (i.e. what happens on prolonged exposure to high temperatures).

Roof Coating Denver Colorado

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